Practical synthesis of diaryliodonium(III) triflates using ArI(OAc)2/TfOH/MeCN reaction system was written by Komiyama, K.;Kobayashi, S.;Shoji, T.;Kikushima, K.;Dohi, T.;Kita, Y.. And the article was included in Russian Chemical Bulletin in 2020.Category: iodides-buliding-blocks The following contents are mentioned in the article:
Diaryliodonium(III) triflates Ar(Ar1)I+-OS(O)2CF3 (Ar = Ph, 2-bromophenyl, 2,4,6-trimethylphenyl, etc.; Ar1 = 4-methylphenyl, 4-methoxy-2-(methoxycarbonyl)benzen-1-yl, thiophen-2-yl, etc.) and 3-(p-tolyliodonio)pyridin-1-ium/3-(p-tolyliodonio)quinolin-1-ium bistriflates were synthesized in a safe manner by the reaction of aryliodine(III) diacetates ArI(OAc)2 and 3-(diacetoxyiodo)pyridine/3-(diacetoxyiodo)quinoline trifluoromethanesulfonic acids, aromatic compounds Ar1H with triflic acid (TfOH) in MeCN under mild exothermic conditions. This method provides access to a variety of diaryliodonium(III) triflates, including derivatives with two different aryl substituents, with high purity. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Category: iodides-buliding-blocks).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles. It is used in perfumery and in making tryptophan, an essential amino acid, and indoleacetic acid (heteroauxin), a hormone that promotes the development of roots in plant cuttings.Category: iodides-buliding-blocks
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com