Organocatalytic Synthesis of Phenols from Diaryliodonium Salts with Water under Metal-Free Conditions was written by Katagiri, Kotone;Kuriyama, Masami;Yamamoto, Kosuke;Demizu, Yosuke;Onomura, Osamu. And the article was included in Organic Letters in 2022.Application of 139139-80-3 The following contents are mentioned in the article:
The metal-free synthesis of phenols ArOH [Ar = 4-MeC6H4, 3-MeC6H4, 4-ClC6H4, etc.] from diaryliodonium salts with water was developed by using N-benzylpyridin-2-one as an organocatalyst. In this process, sterically congested, functionalized, and heterocycle-containing iodonium salts were smoothly converted to the desired products, and the clofibrate and mecloqualone derivatives were also synthesized in high yields. In addition, the gram-scale experiment was successfully carried out with 10 mmol of a sterically congested substrate. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Application of 139139-80-3).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. In addition to tryptophan, indigo, and indoleacetic acid, numerous compounds obtainable from plant or animal sources contain the indole molecular structure. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Application of 139139-80-3
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com