Ruthenium(II)-Catalyzed Chelation-Assisted Arylation of C-H Bonds with Diaryliodonium Salts was written by Ho, Jordan Sun;Misal Castro, Luis C.;Aihara, Yoshinori;Tobisu, Mamoru;Chatani, Naoto. And the article was included in Asian Journal of Organic Chemistry in 2014.COA of Formula: C17H18F3IO3S The following contents are mentioned in the article:
Synthesis of teraryls I (R1 = Me, R2 = H, R3 = H, 4-Me, 4-EtO2C, 3-EtO2C, 4-Br, 4-MeO; R1 = Me, R2 = 4-MeO, 4-MeO2C, 5-CF3, 4-acetyl, R3 = H; R1 = R3 = H, R2 = 6-Me) via chelation-assisted arylation of the ortho C-H bonds in 2-arylpyridine derivatives was achieved by using [Ru(OAc)2(p-cymene)] as catalyst and diaryliodonium salts as arylation reagent. The reaction tolerated a broad range of functional groups and appeared to proceed by a mechanism similar to Pd-catalyzed C-H arylation. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4COA of Formula: C17H18F3IO3S).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. The indole subunit is an almost ubiquitous component of biologically active natural products, and its study has been the focus of research for decades. More than 200 indole derivatives have already been marketed as drugs or are under advanced stages of clinical trials.COA of Formula: C17H18F3IO3S
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com