Elsherbini, Mohamed et al. published their research in Organic & Biomolecular Chemistry in 2021 | CAS: 1204518-02-4

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. Moreover, it is known that it controls biofilm formation. However, the role of indole in the cell has not been fully elucidated.Related Products of 1204518-02-4

Scalable electrochemical synthesis of diaryliodonium salts was written by Elsherbini, Mohamed;Moran, Wesley J.. And the article was included in Organic & Biomolecular Chemistry in 2021.Related Products of 1204518-02-4 The following contents are mentioned in the article:

Cyclic and acyclic diaryliodoniums I (R = H, 2-Me, 8-F, 6,8-(Me)2, 7-CF3; R1 = 2-F, 7-Cl, 2-OMe, etc.) and II (R2 = 4-F, 4-Br, 2-Ph, etc.; R3 = H, 4-I, 4-Me, 2,4,6-(Me)3) are synthesized by anodic oxidation of iodobiaryls III and iodoarenes R2C6H4I/arene R3C6H5 mixtures, resp., in a simple undivided electrolysis cell in MeCN-HFIP-TfOH without any added electrolyte salts. This atom efficient process does not require chem. oxidants and generates no chem. waste. More than 30 cyclic and acyclic diaryliodonium salts I with different substitution patterns were prepared in very good to excellent yields. The reaction was scaled-up to 10 mmol scale giving more than four grams of dibenzo[b,d]iodol-5-ium trifluoromethanesulfonate I (>95%) in less than three hours. The solvent mixture of the large-scale experiment was recovered (>97%) and recycled several times without significant reduction in yield. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Related Products of 1204518-02-4).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. Moreover, it is known that it controls biofilm formation. However, the role of indole in the cell has not been fully elucidated.Related Products of 1204518-02-4

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com