Versatile and base-free copper-catalyzed α-arylations of aromatic ketones using diaryliodonium salts was written by Bouquin, Maxime;Jaroschik, Florian;Taillefer, Marc. And the article was included in Tetrahedron Letters in 2021.Computed Properties of C19H22F3IO3S The following contents are mentioned in the article:
A ligand and base-free copper catalyzed synthetic method for the efficient α-arylation of aromatic ketones ArC(O)CH2Ar1 [Ar = Ph, 4-BrC6H4, 2-thienyl, etc.; Ar1 = Ph, 2-MeC6H4, 4-FC6H4, etc.] was described. In order to avoid strong bases, ketone-derived silyl enol ethers were employed. Their reaction with diaryliodonium salts as aryl source provided the intermol. C-C coupling displaying good functional group tolerance and requiring low catalyst loading. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Computed Properties of C19H22F3IO3S).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles. It is used in perfumery and in making tryptophan, an essential amino acid, and indoleacetic acid (heteroauxin), a hormone that promotes the development of roots in plant cuttings.Computed Properties of C19H22F3IO3S
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com