Ara, Rifat published the artcileChemistry, urease inhibition, and phytotoxic studies of binuclear vanadium(IV) complexes, Formula: C7H7IN2O, the publication is Chemistry & Biodiversity (2007), 4(1), 58-71, database is CAplus and MEDLINE.
Vanadium plays an important role in biol. systems and exhibits a variety of bioactivities. In an effort to uncover the chem. and biochem. of vanadium with nitrogen- and oxygen-containing ligands, we report herein the synthesis and spectroscopic characterization of vanadium(IV) complexes with hydrazide ligands. Substituents on these ligands exhibit systematic variations of electronic and steric factors. Elemental and spectral data indicate the presence of a dimeric unit with two vanadium(IV) ions coordinated with two hydrazide ligands along with two H2O mols. The stability studies of these complexes over time in coordinating solvent, DMSO, indicates binding of the solvent mols. to give [V2O2L2(H2O)2(DMSO)2]2+ (L = hydrazide ligand) and then conversion of it to a monomeric intermediate species, [VOL(DMSO)3]1+. Hydrazide ligands are inactive against urease, whereas vanadium(IV) complexes of these ligands show significant inhibitory potential against this enzyme and are found to be non-competitive inhibitors. These complexes also show low phytotoxicity indicating their usefulness for soil ureases. Structure-activity relationship studies indicate that the steric and/or electronic effects that may change the geometry of the complexes play an important role in their inhibitory potential and phytotoxicity.
Chemistry & Biodiversity published new progress about 39115-95-2. 39115-95-2 belongs to iodides-buliding-blocks, auxiliary class Iodide,Hydrazine,Amine,Benzene,Hydrazide,Amide, name is 4-Iodobenzohydrazide, and the molecular formula is C7H7IN2O, Formula: C7H7IN2O.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com