Jiang, Wenhao published the artcileEfficient P-Chiral Biaryl Bisphosphorus Ligands for Palladium-Catalyzed Asymmetric Hydrogenation, Recommanded Product: Ethyl 3-(4-iodophenyl)-3-oxopropanoate, the main research area is crystal structure benzooxaphosphole palladium preparation catalyst asym hydrogenation ketocarboxylate; mol structure benzooxaphosphole palladium preparation catalyst asym hydrogenation ketocarboxylate.
Five structurally novel P-chiral bis(benzooxaphosphole) ligands (BABIBOPs) are developed, providing high efficiency for the 1st time in Pd-catalyzed asym. hydrogenation of β-aryl and β-alkyl substituted β-keto esters. With a palladium BABIBOP catalyst, chiral β-hydroxyl carboxylic esters are formed in excellent enantioselectivities (up to>99% ee) and yields at catalyst loading as low as 0.01 mol%.
Chinese Journal of Chemistry published new progress about Crystal structure. 63131-30-6 belongs to class iodides-buliding-blocks, name is Ethyl 3-(4-iodophenyl)-3-oxopropanoate, and the molecular formula is C11H11IO3, Recommanded Product: Ethyl 3-(4-iodophenyl)-3-oxopropanoate.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com