Chen, Qiwei published the artcileSteering On-Surface Reactions by a Self-Assembly Approach, SDS of cas: 685517-67-3, the main research area is on surface synthesis functional nanostructure preparation; difluoropyridnyl terphenyl self assembly mediated reaction gold surface; scanning tunneling microscopy assessment self assembly reaction gold surface; density functional theory calculation self assembly reaction gold surface; self assembly reaction gold surface scanning tunneling microscopy; dehydrocyclization coupling reaction difluoropyridnyl terphenyl gold surface; dehydrocyclization; density functional theory; on-surface reaction; scanning tunneling microscope; self-assembly.
4,4′-Bis(2,6-difluoropyridin-4-yl)-1,1′:4′,1”-terphenyl (BDFPTP) mols. underwent dehydrocyclization and covalent coupling reactions on Au(111) according to scanning tunneling microscopy measurements and d. functional theory calculations Self-assembly of the reactants in well-defined mol. domains prior to reaction greatly enhances the regio-selectivity of the dehydrocyclization reaction and suppressed defluorinated coupling, demonstrating that self-assembly can efficiently steer on-surface reactions. Such a strategy could be greatly important for surface chem. and widely used to control on-surface reactions.
Angewandte Chemie, International Edition published new progress about Coupling reaction (defluorinated). 685517-67-3 belongs to class iodides-buliding-blocks, name is 2,6-Difluoro-3-iodopyridine, and the molecular formula is C5H2F2IN, SDS of cas: 685517-67-3.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com