On June 13, 2006, Vasylyev, Maxym; Neumann, Ronny published an article.Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane The title of the article was Preparation, characterization, and catalytic aerobic oxidation by a vanadium phosphonate mesoporous material constructed from a dendritic tetraphosphonate. And the article contained the following:
Reaction of neat V(O)(OiPr)3 with 1,3,5,7-tetrakis(4-phosphonatophenyl)adamantane (TPPhA) afforded a vanadium phosphonate mesoporous material, with V:P ratio of 1:1 and formula C34H28O16P4V4/10H2O. The N2 sorption isotherm is consistent with a mesoporous material, with pore size maximum of 38-39 脜 in the distribution curve. The compound was further characterized by powder XRD, TEM, EPR and SEM. The product is effective as catalyst for aerobic oxidation of benzylic alcs. to benzaldehydes. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane
The Article related to vanadium phosphonatophenyladamantane mesoporous material preparation, oxidation catalyst benzyl alc mesoporous vanadium dendritic tetraphosphonate, Inorganic Chemicals and Reactions: Metal-Containing Salts and Related Metal-Containing Compounds and other aspects.Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com