On March 31, 1993, Reichert, Veronica R.; Mathias, Lon J. published an article.Related Products of 144970-30-9 The title of the article was Rigid-expanded tetrahedral cores for four-armed branched structures: 1,3,5,7-tetrakis(4-iodophenyl)adamantane and its derivatives. And the article contained the following:
1,3,5,7-Tetrakis(4-iodophenyl)adamantane (I) was an ideal starting material for the preparation of rigid, expanded tetrahedral core mols. Pd-catalyzed coupling of I with 1-decene gave acceptable yields of 1,3,5,7-tetrakis(1-decenyl)adamantane, a model for all-hydrocarbon star-polymer systems. 1,3,5,7-Tetrakis(4-carboxyphenyl)adamantane (II) was obtained from a Grignard-type reaction of I with sec-BuLi followed by reaction with CO2 and acidification. Direct condensation of II with 1-aminoadamantane in the presence of triphenylphosphine and hexachloroethane gave the tetra-adamantyl amide. These monomers could be used for the preparation of macromols. with enforced 3-dimensional structures. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Related Products of 144970-30-9
The Article related to tetrakisiodophenyl adamantane preparation, tetrahedral adamantane derivative nmr spectrum, ir spectrum tetrahedral adamantane derivative, Chemistry of Synthetic High Polymers: Monomers and Reagents Used In Polymerization and other aspects.Related Products of 144970-30-9
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com