On December 13, 2021, Okayasu, Misaki; Sunakawa, Toshiki; Ikeda, Mitsuru; Namikawa, Takaya; Hagura, Riho; Kikkawa, Shoko; Hikawa, Hidemasa; Azumaya, Isao published an article.Safety of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane The title of the article was Size and Shape Manipulation of Channel Structures Assembled Via Saddle stacking of Tetrapodal Adamantanes Containing Aryl Butadiynyl Moieties. And the article contained the following:
Three tetrapodal adamantane derivatives containing aryl butadiynyl moieties were synthesized under conditions similar to those of the Hay coupling reaction, and their crystal structures were analyzed. The substituted tetrapodal adamantanes were found to pile atop each other via saddle stacking to form 1D columnar structures, and the assembly of these 1D structures gave rise to channels in the crystal. Column assembly was achieved through CH/蟺 and 蟺-蟺 interactions between the terminal aromatic rings of the adamantanes belonging to adjacent columns. The channels thus formed had different shapes and sizes depending on the terminal aryl substituents, and were occupied by a suitable number of solvent mols. Compared to the adamantanes with Ph butadiynyl moieties as the terminal substituents, those with naphthyl butadiynyl moieties formed wider or thicker channels owing to their greater expanse perpendicular to the direction of saddle-stacking. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Safety of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane
The Article related to tetrakis arylbutadiynyl phenyl adamantane preparation, Alicyclic Compounds: Tricyclic Compounds and Higher Analogs, Including Adamantanes, Fullerenes and other aspects.Safety of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com