On December 10, 2015, Grammenos, Wassilios; Boudet, Nadege; Mueller, Bernd; Escribano Cuesta, Ana; Lohmann, Jan Klaas; Grote, Thomas; Craig, Ian Robert; Fehr, Marcus; Quintero Palomar, Maria Angelica; Lauterwasser, Erica May Wilson; Kretschmer, Manuel published a patent.Product Details of 364-12-5 The title of the patent was Preparation of substituted [1,2,4]triazole compounds as agrochemical fungicides. And the patent contained the following:
The present invention relates to compounds of the formula I [R1 = each (un)substituted C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, or C3-6 cycloalkyl; R2 = H or each (un)substituted C1-4 alkyl, C2-4 alkenyl, or C2-4 alkynyl; R3 = H, halogen, cyano, or each (un)substituted C1-4 alkyl, C1-4 alkoxy, C2-4 alkenyl, C2-4 alkynyl, C3-6 cycloalkyl, or S(O)p(C1-4 alkyl), wherein p = 0-2; R4, R5, R6 = independently H, halogen, or each (un)substituted C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, C1-4 alkoxy, C3-6 cycloalkyl, C3-6 cycloalkenyl, C3-6 cycloalkyl-C1-4 alkyl, -N(Ra)2, C3-6 halogencycloalkyl, aryl, or aryloxy; R4 and R5 together are =O, and R6 is as defined above; R4 and R5 together are :C(Ra)2, and R6 is as defined above and Ra is as defined below; or R4 and R5 together form a carbocycle or heterocycle, and R6 is as defined above; Ra = independently halogen, OH, cyano, C1-4 alkyl, C1-4 halogenalkyl, C3-6 cycloalkyl, C3-6 halogencycloalkyl, C1-4 alkoxy, C1-4 halogenalkoxy, or and Si(C1-4 alkyl)3; X = O, S(O)n, wherein n = 0-2, or (un)substituted NH] and the N-oxides and the agriculturally acceptable salts thereof. These compounds have an improved activity and/or a broader activity spectrum against phytopathogenic harmful fungi and are useful for combating phytopathogenic fungi in plants or seeds. Thus, a mixture of 3-chloro-4-[1-cyclopropyl-1-hydroxy-2-(1,2,4-triazol-1-yl)ethyl]phenol 500, Cs2CO3 870, and dibromotetrafluoroethane 930 mg in 5 mL DMSO was heated to 50掳 for 3 days to give, after workup, 1-[4-(2-bromo-1,1,2,2-tetrafluoroethoxy)-2-chlorophenyl]-1-cyclopropyl-2-(1H-1,2,4-triazol-1-yl)ethanol (II) as a yellow oil. One invention compound (III) completely controlled the growth of gray mold Botrytis cinerea at 31 ppm, rice blast Pyricuiaria oryzae at 31 ppm, and leaf blotch on wheat caused by Septoria tritici at 8 ppm. The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Product Details of 364-12-5
The Article related to triazole preparation agrochem fungicide, phenylcyclopropyltriazolylethanol preparation agrochem fungicide, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.Product Details of 364-12-5
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com