Yoshida, Suguru; Shimomori, Ken; Kim, Youngchan; Hosoya, Takamitsu published an article in 2016, the title of the article was Single C-F Bond Cleavage of Trifluoromethylarenes with an ortho-Silyl Group.Quality Control of 5-Bromo-2-iodobenzotrifluoride And the article contains the following content:
The transformation of a single C-F bond of trifluoromethylarenes bearing a hydrosilyl group at the ortho position was achieved. The activation of the hydrosilyl group with a trityl cation in the presence of nucleophiles allowed for selective C-F bond functionalization, for example, by allylation, carboxylation, or chlorination. Further derivatization of the resulting fluorosilylarenes afforded various aromatic difluoromethylene compounds The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Quality Control of 5-Bromo-2-iodobenzotrifluoride
The Article related to silylbenzotrifluoride preparation defluorinative monoallylation allyltrimethylsilane trityl cation, fluorobutenyl fluorosilylarene preparation, c−f activation, allylation, fluorine, silanes, trityl cation and other aspects.Quality Control of 5-Bromo-2-iodobenzotrifluoride
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com