On November 21, 2009, Plietzsch, Oliver; Schilling, Christine Inge; Tolev, Mariyan; Nieger, Martin; Richert, Clemens; Muller, Thierry; Brase, Stefan published an article.Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane The title of the article was Four-fold click reactions: Generation of tetrahedral methane- and adamantane-based building blocks for higher-order molecular assemblies. And the article contained the following:
A modular concept for the generation of achiral and chiral non-racemic tetrahedral tectons from common precursors was developed. The tectons presented here are based on tetraphenylmethane or 1,3,5,7-tetraphenyladamantane core structures. They are obtained through high-yielding four-fold click reactions, using either the tetraazido or the tetraalkyne precursors. In most cases, the tetratriazoles are obtained as pure products after simple washing with water and methanol. The side chains of the tectons prepared include a self-complementary DNA dimer, obtained from a 3′-azidonucleoside and a phosphoramidite. The concept allows for a variation of the “sticky ends”, leading to tecton or ligand libraries. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane
The Article related to tetrahedral methane adamantane tecton triazole preparation, amine azidation azide alkyne click chem, dipolar cycloaddition copper catalyst, dna dimer dinucleotide preparation azidonucleoside phosphoramidite and other aspects.Application In Synthesis of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com