Boldog, Ishtvan; Domasevitch, Konstantin V.; Baburin, Igor A.; Ott, Holger; Gil-Hernandez, Beatriz; Sanchiz, Joaquin; Janiak, Christoph published an article in 2013, the title of the article was A rare alb-4,8-Cmce metal-coordination network based on tetrazolate and phosphonate functionalized 1,3,5,7-tetraphenyladamantane.Recommanded Product: 144970-30-9 And the article contains the following content:
Sym. tetrahedral ligands are prominent, but somewhat under-studied building blocks for the generation of coordination polymeric networks. Coordination networks [Mn5Cl2(L1)2(H2O)4(DMF)4]·3H2O·7DMF, 1 and the [La2(H5L2)2(H2O)6], 2 were synthesized under mild solvothermal methods in DMF from the adamantane-based tetrahedral ligands, 1,3,5,7-tetrakis(4-phenyltetrazol-5-yl)adamantane (H4L1), reported for the first time, and 1,3,5,7-tetrakis(4-phenylphosphonic acid)adamantane (H8L2), resp. Compounds 1 and 2 are based on completely different pentanuclear and binuclear secondary metal building units, resp., and have different symmetries, but demonstrate an interesting coincidence of underlying topologies, which could be interpreted as a directing or imprinting’ effect of the symmetry of the rigid tetrahedral ligands. Both structures represent examples of a rarely observed (4,8)-coordinated net. The χMT product for 1 at room temperature is slightly lower than the expected for five Mn(II) ions with S = 5/2 and g ≈ 1.98 and on lowering the temperature χMT approaches the expected value for a single Mn(II) as a result of the antiferromagnetic coupling through the tetrazolate bridges. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Recommanded Product: 144970-30-9
The Article related to manganese lanthanum tetrazolate phosphonate tetraphenyladamantane complex preparation crystal structure, magnetic property manganese lanthanum tetrazolate phosphonate functionalized tetraphenyladamantane complex and other aspects.Recommanded Product: 144970-30-9
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