In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline.Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles. Application In Synthesis of 626-01-7.
Sheikh, Safoora;Nasseri, Mohammad Ali;Chahkandi, Mohammad;Reiser, Oliver;Allahresani, Ali research published 《 Dendritic structured palladium complexes: Magnetically retrievable, highly efficient heterogeneous nanocatalyst for Suzuki and Heck cross-coupling reactions》, the research content is summarized as follows. The recyclable nanomagnetic Pd-complex PAMAM G0-Pd@γ-Fe2O3 is reported for catalytic C-C cross-coupling reactions of challenging substrates. Mainly, a great variety of aryl chlorides could be used as substrates for Suzuki-Miyaura and Mizoroki-Heck reactions under mild reaction conditions (60-90°C) and low catalyst loading (<1 mol% Pd) in aqueous media. A series of biaryls I [R = H, 4-MeO, 4-Me, 4-NO2, 3-NO2, 4-cyano, R1 = 4-MeO, 4-Me, H, 4-CHO, 4-COMe, 4-NO2, 4-cyano, 3-NH2, 3-CF3, 3-NO2, 2-Me, 2-CO2H, 2-NO2, 2-Me-4-NO2] was obtained via Pd-complex catalyzed Suzuki-Miyaura cross-coupling reaction of phenylboronic acids with aryl halides. Also, styrenes and trans-Bu cinnamates II [R3 = 4-Me, 4-MeO, H, 4-cyano, 4-NO2, 4-Br, 4-CO2Et, 4-COMe, 2-Me, R4 = Ph; R3 = H, 4-HO, 4-NH2, 4-MeO, 4-Me, 4-Cl, 3-Me, 3-NO2, R4 = CO2Bu] were obtained via Pd-complex catalyzed Mizoroki-Heck cross-coupling reaction of alkenes and aryl halides. The presence of numerous polar groups in the polymer matrix increased the solubility of the catalyst in water, thus facilitating its operation in aqueous environments. The immobilization of the catalyst on the surface of a magnetic platform allows its effective recovery and reuse without significant loss of catalytic activity for at least six cycles with total leaching of <1% palladium metal, meeting the requirements for acceptable metal residues in the pharmaceutical industry.
626-01-7, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.
3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., Application In Synthesis of 626-01-7
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com