On July 5, 2004, Tohma, Hirofumi; Maruyama, Akinobu; Maeda, Akihisa; Maegawa, Tomohiro; Dohi, Toshifumi; Shiro, Motoo; Morita, Tetsuichiro; Kita, Yasuyuki published an article.Name: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane The title of the article was Preparation and reactivity of 1,3,5,7-tetrakis[4-(diacetoxyiodo)phenyl]adamantane, a recyclable hypervalent iodine(III) reagent. And the article contained the following:
A wide range of oxidative reactions are mediated by novel, nonpolymeric, and recyclable hypervalent IIII reagents [e.g. I, R = I(OAc)2]. In all cases, tetraiodide I (R = I) was recovered nearly quant. in pure form after a simple workup. Reoxidation of I (R = I) to I [R = I(OAc)2] with m-chloroperbenzoic acid also proceeded quant., without loss of oxidative activity. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Name: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane
The Article related to tetrakisdiacetoxyiodophenyladamantane recyclable oxidizing agent preparation, recyclable hypervalent iodine reagent preparation, diacetoxyiodophenyladamantane tetrakis recyclable oxidizing agent preparation, adamantane tetrakisdiacetoxyiodophenyl recyclable oxidizing agent preparation and other aspects.Name: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com