On February 3, 2016, Patil, Komal M.; Dickinson, Michelle E.; Tremlett, Thomas; Moratti, Stephen C.; Hanton, Lyall R. published an article.Category: iodides-buliding-blocks The title of the article was Synthesis of Diamondoid and Lonsdaleite Networks from the Same Ag(I)-Ligand Combination, with Lonsdaleite the Softer Network. And the article contained the following:
The design and synthesis of a Lonsdaleite (lon) network is an attractive and challenging supramol. target. The authors’ reticular synthesis strategy of slow diffusion of solutions of a simple rigid tetrahedral ligand and a Ag(I) metal ion, at room temperature and atm. pressure, resulted in both lon-MOFs and diamondoid (dia-MOFs) and associated 2D honeycomb networks. The prepared complexes are {[AgL]X.nCH3NO2} [X = CF3SO3-, n = 4 (1a, 1); BF4-, n = 3 (1b, 2); CF3CO2-, n = 5.5 (1c, 3); BF4-, n = 4 (1d, 4)] and interpenetrated dia {[AgL]X.nH2O} [X = PF6-, n = 2 (2a, 5); BF4-, n = 3 (2b, 6); ClO4-, n = 2 (2c, 7), CF3SO3- (2d, 8)] networks along with their associated 2D honeycomb (hcb) networks {[AgL](CF3SO3).2CH3NO2.H2O} (3a, 9) and {[AgL(NO3)].4CH3NO2.H2O} (3b, 10) (where L = tetrakis(4-cyanophenyl)adamantane). Solvent appeared to play a key role in templating the formation of these related networks. Nanoindentation studies show that a dia-MOF was 42% harder than a lon-MOF counterpart. The lon-MOFs were thermally stable and retained integrity until 370° while dia-MOFs exhibited stepwise collapse after initial loss of solvents. As lon networks are often only qual. identified, Cremer-Pople ring puckering anal. was used to quantify the degree of distortion in the lon and related 4-connected 66 networks. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Category: iodides-buliding-blocks
The Article related to preparation diamondoid lonsdaleite network silver cyanophenyladamantane network complex, crystal structure diamondoid lonsdaleite network silver cyanophenyladamantane network complex, thermal decomposition diamondoid lonsdaleite network silver cyanophenyladamantane network complex and other aspects.Category: iodides-buliding-blocks
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com