Zhu, Daoyong; Xu, Wenqiang; Pu, Maoping; Wu, Yun-Dong; Chi, Yonggui Robin; Zhou, Jianrong Steve published an article in 2021. The article was titled 《Asymmetric Domino Heck Arylation and Alkylation of Nonconjugated Dienes: Double C-F···Sodium Attractive Noncovalent Interaction》, and you may find the article in Organic Letters.HPLC of Formula: 15164-44-0 The information in the text is summarized as follows:
Palladium catalyzed domino Heck arylation and alkylation of nonconjugated cyclodienes to produce trans isomers of disubstituted cyclohexenes in exceptionally high enantiomeric ratios, reaching 100:1 to 200:1 in many cases. Importantly, the interactions of the two CF bonds of Josiphos and the sodium ion of malonates facilitated stereoselective allylic attack through DFT calculations and experiments This is a new type of attractive noncovalent interactions found in organometallic catalysis. In the experiment, the researchers used 4-Iodobenzaldehyde(cas: 15164-44-0HPLC of Formula: 15164-44-0)
4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.HPLC of Formula: 15164-44-0
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com