Application of 63069-48-7In 2021 ,《Quasi-homogeneous catalytic conversion of CO2 into quinazolinones inside a metal-organic framework microreactor》 appeared in Green Chemistry. The author of the article were Zhou, Zhenzhen; Ma, Jian-Gong; Gao, Jianbo; Cheng, Peng. The article conveys some information:
Management of CO2 has been attracting great attention in this century. Reaction of CO2 with 2-haloanilines and isocyanides is an attractive way for both converting CO2 and producing quinazolinones, which are key intermediates for the synthesis of various biol. active products. However, the heterogeneous and relatively inert nature of CO2 with 2-haloaniline and isocyanide reactants limits the types of suitable catalysts. Herein, we use metal-organic frameworks (MOFs) as a “”microreactor””, in which Pd(PPh3)2Cl2 is well-dispersed as a single-mol. catalyst, and the reactants react in the mol. level through a “”quasi-homogeneous”” way to convert CO2 into quinazolinones under mild conditions with both promising yields over homogeneous catalysts and good recyclability as a heterogeneous reaction. The MOF-assisted single-mol. catalysis strategy should contribute to CO2 conversion, production of quinazolinone-type bioactive intermediates, and the epochal development of “”homo-and-heterogeneous”” catalysis. In addition to this study using 4-Chloro-2-iodoaniline, there are many other studies that have used 4-Chloro-2-iodoaniline(cas: 63069-48-7Application of 63069-48-7) was used in this study.
4-Chloro-2-iodoaniline(cas: 63069-48-7) belongs to anime. Amines have a free lone pair with which they can coordinate to metal centers. Amine–metal bonds are weaker because amines are incapable of backbonding, but they are still important for sensing applications.While stronger than hydrogen bonds, amine–metal bonds are still weaker than both covalent and ionic bonds.Application of 63069-48-7
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com