Product Details of 15164-44-0In 2020 ,《Controllable double CF2-insertion into sp2 C-Cu bond using TMSCF3: a facile access to tetrafluoroethylene-bridged structures》 was published in Chemical Science. The article was written by Xie, Qiqiang; Zhu, Ziyue; Li, Lingchun; Ni, Chuanfa; Hu, Jinbo. The article contains the following contents:
A highly efficient method for controllable double CF2-insertion into pentafluorophenylcopper species using TMSCF3 as difluoromethylene source had been developed. The newly generated fluoroalkylcopper(I) species, C6F5CF2CF3Cu, showed good reactivity toward a myriad of structurally diverse aryl, heteroaryl and alkenyl iodides. This protocol was easy to handle, ready to scale up and applicable for the synthesis of relative complex mols., thus providing a convenient method for facile access to tetrafluoroethylene-bridged structures C6F5CF2CF2R [R = 2-thienyl, Ph, 4-NCC6H4, etc.].4-Iodobenzaldehyde(cas: 15164-44-0Product Details of 15164-44-0) was used in this study.
4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Product Details of 15164-44-0
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com