In 2022,Wang, Wei; Yao, Ken; Wu, Fan published an article in Synlett. The title of the article was 《Nickel-Catalyzed Reductive Cross-Coupling of Benzylic Sulfonium Salts with Aryl Iodides》.Related Products of 15164-44-0 The author mentioned the following in the article:
A nickel-catalyzed cross-electrophile coupling of benzylic sulfonium salts R1CH(S+(CH3)2)R2·O-S(O)CF3 [R1 = Ph, naphthalen-2-yl, benzo[d][1,3]dioxol-5-yl, etc.; R2 = H, Me, Et] with aryl iodides R3I [R3 = 4-carboxymethylphenyl, 9H-fluoren-2-yl, 4-formylphenyl, etc.] has been developed, providing direct access to diarylalkanes R1CH(R2)R3 from readily available and stable coupling partners. Preliminary mechanistic studies suggest that the C-S bond cleavage proceeds through a single-electron transfer process to generate a benzylic radical. After reading the article, we found that the author used 4-Iodobenzaldehyde(cas: 15164-44-0Related Products of 15164-44-0)
4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Related Products of 15164-44-0
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com