《Design and synthesis of a chiral halogen-bond donor with a Sp3-hybridized carbon-iodine moiety in a chiral fluorobissulfonyl scaffold》 was written by Uno, Hiroto; Matsuzaki, Kohei; Shiro, Motoo; Shibata, Norio. SDS of cas: 189518-78-3 And the article was included in Molecules in 2020. The article conveys some information:
The first example of a chiral halogen-bond donor with a sp3-hybridized carbon-iodine moiety in a fluorobissulfonyl scaffold was described. The binaphthyl backbone was designed as a chiral source and the chiral halogen-bond donor I, was synthesized from (R)-1,1′-binaphthol in 11 steps. An NMR titration experiment demonstrated that I worked as a halogen-bond donor. The Mukaiyama aldol reaction and quinoline reduction were examined using I as a catalyst to evaluate the asym. induction. In the part of experimental materials, we found many familiar compounds, such as (R)-3,3′-Diiodo-2,2′-bis(methoxymethoxy)-1,1′-binaphthalene(cas: 189518-78-3SDS of cas: 189518-78-3)
(R)-3,3′-Diiodo-2,2′-bis(methoxymethoxy)-1,1′-binaphthalene(cas: 189518-78-3) belongs to organic iodides. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. SDS of cas: 189518-78-3 Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com