Shan, Zi-Wei; Chen, Xiao-Yan; Zhang, Hao; Liu, Hai-Yang; Yuan, Gao-Qing published an article in 2022. The article was titled 《Copper Porphyrin Catalyzed C(sp3)-H Activation via Cross-Dehydrogenative Coupling: Facile Transformation of Aldehydes to Esters》, and you may find the article in Synlett.Recommanded Product: 15164-44-0 The information in the text is summarized as follows:
Copper porphyrin catalyzed alkane C-H bond functionalization with aldehydes via cross-dehydrogenative coupling (CDC) using DTBP oxidant has been firstly described in nonsolvents or nonadditives system. Different aryl/heteroaryl carboxylic esters were obtained in good to excellent yields depending on the aldehyde derivatives This CDC reaction catalyzed by copper porphyrin has the advantages of shorter reaction time, lower reaction temperature, and catalyst loading as well as the aerobic reaction atm. In the part of experimental materials, we found many familiar compounds, such as 4-Iodobenzaldehyde(cas: 15164-44-0Recommanded Product: 15164-44-0)
4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Recommanded Product: 15164-44-0
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com