Miyamoto, Kazunori; Okada, Tomohide; Toyama, Takashi; Imamura, Shinji; Uchiyama, Masanobu published an article in 2021. The article was titled 《Facile preparation of 1-hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide (IBX) and Dess-Martin reagent using sodium hypochlorite under carbon dioxide》, and you may find the article in Heterocycles.Related Products of 88-67-5 The information in the text is summarized as follows:
A safe, convenient, and inexpensive method for preparation of the widely used oxidizing agent 1-hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide (IBX) has been developed, by treatment of 2-iodobenzoic acid with aqueous sodium hypochlorite under CO2 at room temperature As the only byproduct is NaCl, this reaction can be utilized for one-pot synthesis of 1,1,1-triacetoxy-1,2-benziodoxol-3(1H)-one (Dess-Martin reagent) in excellent yield. In the experiment, the researchers used 2-Iodobenzoic acid(cas: 88-67-5Related Products of 88-67-5)
2-Iodobenzoic acid(cas: 88-67-5) belongs to organic iodides.Related Products of 88-67-5 The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com