In 2022,Li, Zhijun; Zhang, Mingyang; Zhang, Lili; Dong, Xiuli; Leng, Leipeng; Horton, J. Hugh; Wang, Jun published an article in Nano Research. The title of the article was 《Engineering the atomic interface of porous ceria nanorod with single palladium atoms for hydrodehalogenation reaction》.Name: 3-Iodophenol The author mentioned the following in the article:
Tuning the electronic properties of single atom catalysts (SACs) between the central metal and the neighboring surface atoms has emerged as an efficient strategy to boost catalytic efficiency and metal utilization. Here we describe a simple and efficient approach to create atomically dispersed palladium atoms supported over defect-contg porous ceria nanorod contg palladium up to 0.26 weight The existence of singly dispersed palladium atoms is confirmed by spherical aberration correction electron microscopy and extended X-ray absorption fine structure measurements. This catalyst shows excellent efficiency in hydrodehalogenation reactions at low H2 pressure under mild conditions, along with satisfactory recyclability and scalability. D. functional theory (DFT) calculations reveal that the high activity stems from the spatial isolation of palladium atoms and the modified electronic structure of palladium confined in defect-containing ceria nanorod. This work may lay the foundation for the facile creation of single atom catalysts within the synthetic community and shed light on the possibility for scale-up prodn graphic not available see fulltext. The results came from multiple reactions, including the reaction of 3-Iodophenol(cas: 626-02-8Name: 3-Iodophenol)
3-Iodophenol(cas: 626-02-8) belongs to organic iodides. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics.Name: 3-IodophenolHalogenation of aromatic hydrocarbons is a very important reaction via an electrophilic aromatic substitution.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com