Hong, Chao; Yu, Shuling; Liu, Zhanxiang; Zhang, Yuhong published an article in 2021. The article was titled 《Rhodium(III)-catalyzed annulation of enamides with sulfoxonium ylides toward isoquinolines》, and you may find the article in RSC Advances.Synthetic Route of C3H9IOS The information in the text is summarized as follows:
An efficient rhodium(III)-catalyzed C-H activation followed by intermol. annulation between enamides and sulfoxonium ylides had been developed. The transformation proceeded smoothly with a broad range of substrates, affording a series of isoquinoline derivatives I [R = Ph, 4-BrC6H4, 2-furyl, etc.; R1 = H, 6-F, 8-MeO, etc; R2 = H, Me, Ph] in moderate to good yields under additive-free conditions. In addition to this study using Trimethylsulfoxonium iodide, there are many other studies that have used Trimethylsulfoxonium iodide(cas: 1774-47-6Synthetic Route of C3H9IOS) was used in this study.
Trimethylsulfoxonium iodide(cas: 1774-47-6) reacts with sodium hydride to prepare dimethyloxosulfonium methylide, which is used as a methylene-transfer reagent in synthetic chemistry. It is used to prepare ylide, which reacts with carbonyl compounds to get epoxides.Synthetic Route of C3H9IOS
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com