Cheng, Sidi; Luo, Yu; Yu, Ting; Li, Jing; Gan, Chunfang; Luo, Shuang; Zhu, Qiang published an article in 2022. The article was titled 《Palladium-Catalyzed Four-Component Cascade Imidoyl-Carbamoylation of Unactivated Alkenes》, and you may find the article in ACS Catalysis.HPLC of Formula: 15164-44-0 The information in the text is summarized as follows:
A 1,2-difunctionalization of an unactivated alkene, imidoyl-carbamoylation were developed through a palladium-catalyzed four-component cascade reaction involving aryl iodide, alkenyl isocyanide, CO and amine. Continuous migratory insertion of three different functionalities to the Pd(II) intermediate generated from the previous step took place in a well-defined sequence. Four chem. bonds, including three C-C bonds and one C-N bond, were formed in this cascade process, leading to a convenient and convergent access to acetamides substituted with five- to seven-membered cyclic ketoimines. In addition, an extra C-N bond was formed through in-situ or postreaction cyclization of the amido NH to the ketoimine moiety, providing a facile one-pot access to pyrrolo-fused heterocycles. The experimental part of the paper was very detailed, including the reaction process of 4-Iodobenzaldehyde(cas: 15164-44-0HPLC of Formula: 15164-44-0)
4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.HPLC of Formula: 15164-44-0
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com