Zubar, Viktoriia; Brzozowska, Aleksandra; Sklyaruk, Jan; Rueping, Magnus published an article in 2022. The article was titled 《Dehydrogenative and Redox-Neutral N-Heterocyclization of Aminoalcohols Catalyzed by Manganese Pincer Complexes》, and you may find the article in Organometallics.Recommanded Product: 4-Chloro-2-iodoaniline The information in the text is summarized as follows:
A new Mn catalyzed heterocyclization of aminoalcs. was accomplished. A wide range of heterocycles were synthesized including, 1,2,3,4-tetrahydroquinolines, dihydroquinolinones and 2,3,4,5-tetrahydro-1H-benzo[b]azepines. The reaction was performed under mild reaction conditions using air and moisture stable Mn catalysts. The desired heterocycles were obtained in good to excellent yields.4-Chloro-2-iodoaniline(cas: 63069-48-7Recommanded Product: 4-Chloro-2-iodoaniline) was used in this study.
4-Chloro-2-iodoaniline(cas: 63069-48-7) belongs to anime. Hydrogen peroxide (H2O2) and peroxy acids generally add an oxygen atom to the nitrogen of amines. With primary amines, this step is normally followed by further oxidation, leading to nitroso compounds, RNO, or nitro compounds, RNO2. Secondary amines are converted to hydroxylamines, R2NOH, and tertiary amines to amine oxides, R3NO.Recommanded Product: 4-Chloro-2-iodoaniline
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com