In 2019,Advanced Synthesis & Catalysis included an article by Tu, Zhi; Du, Yi; Cao, Xiaoji; Liu, Yunyun. SDS of cas: 589-87-7. The article was titled 《Tunable Single and Double γ-C-H Arylation of Phenylacetamides Directed by o-Aminophenols》. The information in the text is summarized as follows:
The cheap and easily available o-aminophenols (OAPs) have been identified as practical directing component for the Pd-catalyzed aromatic γ-C-H bond arylation of phenylacetamides. Notably, the selective single and double arylation of the C-H bond(s) in the γ-potion has been independently realized by simply modifying reaction conditions. The catalytic system of Pd(CF3OO)2/K2S2O8/K2CO3 enables the selective single C-H arylation. On the other hand, the catalysis of Pd(OAc)2 in the presence of KIO3/K2CO3 induces the selective arylation of both γ-C-H bonds. The experimental part of the paper was very detailed, including the reaction process of 1-Bromo-4-iodobenzene(cas: 589-87-7SDS of cas: 589-87-7)
1-Bromo-4-iodobenzene(cas: 589-87-7) has been employed as reagent for in situ desilylation and coupling of silylated alkynes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids), as substrate in copper-free Sonogashira coupling in aqueous acetone in synthesis of β,β,dibromostyrenesSDS of cas: 589-87-7
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com