《Electrochemical and spectroscopic study of 2-iodobenzoic acid and 2-iodosobenzoic acid anodic oxidation in aqueous environment》 was written by Devadas, Balamurugan; Svoboda, Jan; Krupicka, Martin; Bystron, Tomas. Computed Properties of C7H5IO2 And the article was included in Electrochimica Acta in 2020. The article conveys some information:
2-Iodosobenzoic acid and especially IBX represent interesting selective and green hypervalent I oxidants. Mainly due to issues connected with their preparation, use of these compounds is limited to laboratory scale. From this point of view, the electrochem. synthesis represents interesting platform for inherently safer production of these highly valued oxidants. To provoke and allow more intense study in this direction, this work aimed to present basic aspects of electrochem. behavior of these compounds in aqueous environment using several anode materials. A combination of various exptl. approaches in combination with time-dependent d. functional theory calculations allowed determining compounds speciation in a wide range of pH values. The most interesting in this sense is iodoxol ring opening after/during deprotonation of 2-iodosobenzoic acid to 2-iodosobenzoate. This process is accompanied by addition of H2O mol. to the I atom. Using voltammetry and controlled potential preparative batch electrolysis allowed constructing approx. form of Pourbaix diagram of the studied compounds Finally, diffusion coefficients of studied compounds and anodic charge transfer coefficients of oxidation reactions were determined based on detailed anal. of linear voltammograms. The results provide a solid base for further study of electrochem. synthesis of 2-iodosobenzoic acid and IBX in aqueous environment. After reading the article, we found that the author used 2-Iodobenzoic acid(cas: 88-67-5Computed Properties of C7H5IO2)
2-Iodobenzoic acid(cas: 88-67-5) belongs to organic iodides. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. Computed Properties of C7H5IO2 Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com