The author of 《A Mild and Regioselective Synthesis of α-Fluoroketones via Gold and Selectfluor Partnership》 were Chen, Xi; Martini, Sophie; Michelet, Veronique. And the article was published in Advanced Synthesis & Catalysis in 2019. Computed Properties of C6H4BrI The author mentioned the following in the article:
Alkynylaryl aldehydes and Me ketones such as I underwent regioselective fluorohydroxylation with Selectfluor in aqueous EtOH in the presence of Ph3PAuCl at ambient temperature to yield α-fluoro ketones such as II. The mechanism of the reaction was studied by the (lack of) reaction of diphenylacetylene and by deuterium labeling and intermediate studies. Selected fluoroketone, including II, were converted to 3-substituted 4-fluoroisoquinolines such as III. In the experiment, the researchers used many compounds, for example, 1-Bromo-3-iodobenzene(cas: 591-18-4Computed Properties of C6H4BrI)
1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Computed Properties of C6H4BrI
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com