Chen, Kun-Quan; Shen, Jie; Wang, Zhi-Xiang; Chen, Xiang-Yu published their research in Chemical Science in 2021. The article was titled 《A donor-acceptor complex enables the synthesis of E-olefins from alcohols, amines and carboxylic acids》.Computed Properties of C10H18INO2 The article contains the following contents:
Herein, a fundamentally distinct strategy enabled by electron donor-acceptor (EDA) complexes was presented for the selective synthesis of olefins from simple and easily available starting materials such as alcs., amines and carboxylic acids. The conversions took place via photoactivation of the EDA complexes of the activated substrates with alkali salts, followed by hydrogen atom elimination from in-situ generated alkyl radicals. This method was operationally simple and straightforward and free of photocatalysts and transition-metals, and showed high regio- and stereoselectivities. In the part of experimental materials, we found many familiar compounds, such as tert-Butyl 4-iodopiperidine-1-carboxylate(cas: 301673-14-3Computed Properties of C10H18INO2)
tert-Butyl 4-iodopiperidine-1-carboxylate(cas: 301673-14-3) is one of organic iodides. Organic iodides are used in veterinary products (Organic Iodide Powder) as a nutritional source of iodine. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs. Oceanic alkyl iodides are believed to be the principal source of atmospheric iodine.Computed Properties of C10H18INO2
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com