Recommanded Product: 626-02-8In 2021 ,《Breathing Room: Restoring Free Rotation in a Schiff-Base Macrocycle through Endoperoxide Formation》 appeared in Organic Letters. The author of the article were Chaudhry, Mohammad T.; Ota, Seiya; Lelj, Francesco; MacLachlan, Mark J.. The article conveys some information:
Macrocyclization is a popular method for preparing hosts, but it can have unintended effects, like limiting mol. free rotation to yield mixtures of inseparable isomers. We report a [3 + 3] Schiff-base macrocycle I (1) with anthracene bridges. Restricted rotation about the phenyl-anthracene bonds leads 1 to exist as a mixture of conformations (1Cs and 1C3v). Macrocycle 1 was photooxidized to tris(endoperoxide) adduct 4, alleviating restricted rotation. These results were supported by spectroscopic, structural, and computational analyses. The results came from multiple reactions, including the reaction of 3-Iodophenol(cas: 626-02-8Recommanded Product: 626-02-8)
3-Iodophenol(cas: 626-02-8) belongs to organic iodides. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics.Recommanded Product: 626-02-8
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com