《Pd(II)-Catalyzed Direct γ-C(sp3)-H Arylation between Free β2-Amino Esters and β3-Amino Esters and Aryl Iodides Using a Catalytic Transient Directing Group》 was published in Journal of Organic Chemistry in 2020. These research results belong to Wang, Zhaohui; Fu, Yangjie; Zhang, Qiyu; Liu, Hong; Wang, Jiang. HPLC of Formula: 591-18-4 The article mentions the following:
Pd(II)-catalyzed direct γ-C(sp3)-H arylation coupling with free β2-amino esters and β3-amino esters using a com. available catalytic transient directing group has been developed. This approach features high efficiency, broad substrate tolerance, easily accessible starting materials, and mild reaction conditions. After reading the article, we found that the author used 1-Bromo-3-iodobenzene(cas: 591-18-4HPLC of Formula: 591-18-4)
1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.HPLC of Formula: 591-18-4 Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com