《Single-Electron Transfer from Dimsyl Anion in the Alkylation of Phenols》 was written by Rohe, Samantha; Revol, Guillaume; Marmin, Thomas; Barriault, Daniel; Barriault, Louis. Synthetic Route of C6H5IO And the article was included in Journal of Organic Chemistry in 2020. The article conveys some information:
While attempting to synthesize biaryl ethers we discovered the inadvertent formation of a methylsulfoxylmethyl ether byproduct. Formation of this unexpected byproduct presented an opportunity to streamline the synthesis of methylsulfoxylmethyl ethers. Mechanistic studies suggest a radical pathway with dimsyl potassium as a reducing agent. The experimental process involved the reaction of 3-Iodophenol(cas: 626-02-8Synthetic Route of C6H5IO)
3-Iodophenol(cas: 626-02-8) belongs to organic iodides.Synthetic Route of C6H5IO The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com