In 2019,Organic & Biomolecular Chemistry included an article by Li, Hongfang; Li, Tao; Hsueh, Yu Jen; Wu, Xue; Xu, Feng; Zhang, Yong Jian. Recommanded Product: 90-14-2. The article was titled 《Tandem arylation and regioselective allylic etherification of 2,3-allenol via Pd/B cooperative catalysis》. The information in the text is summarized as follows:
An efficient method for the construction of arylated allylic ethers ArC(=CH2)CH(OR)CH2OH (Ar = Ph, 2H-1,3-benzodioxol-5-yl, thiophen-2-yl, etc.; R = Et, Bn, cyclohexylmethyl, furan-2-ylmethyl, etc.) was developed via three-component tandem arylation and allylic etherification of 2,3-allenol with aryl iodides ArI and alcs ROH. In the cooperative catalytic system of a palladium complex and triethylborane, the process allows rapid access to functionalized 1-arylvinylated 1,2-diol derivatives in good to high yields with complete branch-selectivities. The synthetic utility of the present process was demonstrated by the late-stage functionalization of a drug mol., the gram-scale synthesis and the elaboration of the products. In the experiment, the researchers used many compounds, for example, 1-Iodonaphthalene(cas: 90-14-2Recommanded Product: 90-14-2)
1-Iodonaphthalene(cas: 90-14-2) is one of organic iodides. Organic iodides are used in veterinary products (Organic Iodide Powder) as a nutritional source of iodine. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs. Oceanic alkyl iodides are believed to be the principal source of atmospheric iodine.Recommanded Product: 90-14-2
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com