In 2022,Galea, Romeric; Blond, Gaelle published an article in Advanced Synthesis & Catalysis. The title of the article was 《Gold(I)-Catalyzed Domino Reaction: An Access to Furooxepines》.Computed Properties of C6H4BrI The author mentioned the following in the article:
The synthesis of [7,5]-fused bicyclic acetals, also named furooxepines I (Ar = 4-chloro-3-fluorophenyl, thiophen-2-yl, naphthalen-2-yl, etc.) through a gold(I)-catalyzed domino reaction was reported. During this transformation, two mols. of homopropargyl alc. ArCC(CH2)2OH react together, in a sequence including intramol. hydroalkoxylation, condensation, 1,6-enyne cycloisomerization, acetalization and isomerization. This gold(I)-catalyzed domino reaction allows the formation of three bonds, two heterocycles and tetrasubstituted carbon stereocenters in a one-step operation with 100% atom economy. Post-functionalizations allow the formation of tetrahydrofurans. In the experiment, the researchers used many compounds, for example, 1-Bromo-3-iodobenzene(cas: 591-18-4Computed Properties of C6H4BrI)
1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Computed Properties of C6H4BrI
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com