Electric Literature of C6H4BrIIn 2021 ,《Strong and Confined Acids Catalyze Asymmetric Intramolecular Hydroarylations of Unactivated Olefins with Indoles》 was published in Journal of the American Chemical Society. The article was written by Zhang, Pinglu; Tsuji, Nobuya; Ouyang, Jie; List, Benjamin. The article contains the following contents:
An efficient and highly enantioselective catalytic asym. intramol. hydroarylation of aliphatic and aromatic olefins with indoles e.g., 3-(4-methyleneoctyl)-1H-benzo[g]indole yielding tetrahydrocarbazoles e.g., I can be realized using strong and confined IDPi Bronsted acid catalysts. This unprecedented transformation is enabled by tertiary carbocation formation and establishes quaternary stereogenic centers in excellent enantioselectivity and with a broad substrate scope that includes an aliphatic iodide, an azide, and an alkyl boronate, which can be further elaborated into bioactive mols. The experimental part of the paper was very detailed, including the reaction process of 1-Bromo-3-iodobenzene(cas: 591-18-4Electric Literature of C6H4BrI)
1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Electric Literature of C6H4BrI
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com