Saha, Debarshi; Maajid Taily, Irshad; Banerjee, Prabal published their research in European Journal of Organic Chemistry in 2021. The article was titled 《Electricity Driven 1,3-Oxohydroxylation of Donor-Acceptor Cyclopropanes: a Mild and Straightforward Access to β-Hydroxy Ketones》.Reference of Trimethylsulfoxonium iodide The article contains the following contents:
An unprecedented external oxidant-free electrochem. protocol for 1, 3-oxohydroxylation of donor-acceptor cyclopropanes is disclosed. The strategy encompasses the activation of the labile π-electron cloud of the aryl ring to cleave the strained Csp3-Csp3 bond of cyclopropane to afford the β-hydroxy ketones via insertion of mol. oxygen. More significantly, based on the detailed mechanistic investigations and cyclic voltammetry experiments, a plausible mechanism is proposed. The experimental part of the paper was very detailed, including the reaction process of Trimethylsulfoxonium iodide(cas: 1774-47-6Reference of Trimethylsulfoxonium iodide)
Trimethylsulfoxonium iodide(cas: 1774-47-6) reacts with sodium hydride to prepare dimethyloxosulfonium methylide, which is used as a methylene-transfer reagent in synthetic chemistry. It is used to prepare ylide, which reacts with carbonyl compounds to get epoxides.Reference of Trimethylsulfoxonium iodide
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com