COA of Formula: C3H9IOSIn 2019 ,《Multifunctionalization of Indoles: Synthesis of 3-Iodo-2-sulfonyl Indoles》 was published in Bulletin of the Korean Chemical Society. The article was written by Park, Hyowon; Bae, Junryeol; Son, Soobin; Jang, Hye-Young. The article contains the following contents:
The selective multifunctionalization of indoles by using thiosulfonates, tri-Me sulfoxonium iodide (Me3SOI), and H2O2 was studied. The reaction of thiosulfonates with Me3SOI and H2O2 produced sulfonyl radicals and an iodination reagent, both of which were incorporated in indoles to form 3-iodo-2-sulfonyl indoles under carefully controlled conditions. The related reaction mechanism and the substrate scope of 3-iodo-2-sulfonyl indoles are presented. In addition to this study using Trimethylsulfoxonium iodide, there are many other studies that have used Trimethylsulfoxonium iodide(cas: 1774-47-6COA of Formula: C3H9IOS) was used in this study.
Trimethylsulfoxonium iodide(cas: 1774-47-6) is a sulfoxonium salt. It is used to generate dimethyloxosulfonium methylide by reaction with sodium hydride. The latter compound is used as a methylene-transfer reagent, and is used to prepare epoxides.COA of Formula: C3H9IOS
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com