In 2019,Journal of the American Chemical Society included an article by Lyu, Hairong; Zhang, Jie; Yang, Jingting; Quan, Yangjian; Xie, Zuowei. HPLC of Formula: 589-87-7. The article was titled 《Catalytic Regioselective Cage B(8)-H Arylation of o-Carboranes via “”Cage-Walking”” Strategy》. The information in the text is summarized as follows:
A proof-of-concept example of catalytic regioselective cage B(8)-H functionalization of o-carboranes was disclosed for the 1st time. Under the help of an acylamino directing group at cage B(3), B(8)-arylated, B(4,7,8)-triarylated and B(4,7,8)-trifluorinated o-carborane derivatives were conveniently prepared From isolation of a key intermediate, D labeling experiments and DFT calculations, a reaction mechanism involving a high-valent Pd induced cage-walking from B(4) to B(8) vertex is proposed to account for the regioselective B(8)-H activation. In the experiment, the researchers used many compounds, for example, 1-Bromo-4-iodobenzene(cas: 589-87-7HPLC of Formula: 589-87-7)
1-Bromo-4-iodobenzene(cas: 589-87-7) has been employed as reagent for in situ desilylation and coupling of silylated alkynes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids), as substrate in copper-free Sonogashira coupling in aqueous acetone in synthesis of β,β,dibromostyrenesHPLC of Formula: 589-87-7
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com