Application In Synthesis of 1-IodonaphthaleneIn 2019 ,《Nickel Catalyzed Intermolecular Carbonyl Addition of Aryl Halide》 was published in European Journal of Organic Chemistry. The article was written by Ishida, Seima; Suzuki, Hiroyuki; Uchida, Seiichiro; Yamaguchi, Eiji; Itoh, Akichika. The article contains the following contents:
In this study, we develop a nickel-catalyzed carbonyl arylation reaction employing aldehydes with aryl and allyl halides. Various aryl, α,β-unsaturated aldehyde and aliphatic aldehydes can be converted into their corresponding secondary alcs. in moderate-to-high yields. In addition, we extended this approach to develop an asym. reductive coupling reaction that combines nickel salts with chiral bisoxazoline ligands to give secondary alcs. with moderate enantioselectivity. In the experimental materials used by the author, we found 1-Iodonaphthalene(cas: 90-14-2Application In Synthesis of 1-Iodonaphthalene)
1-Iodonaphthalene(cas: 90-14-2) is one of organic iodides. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles.Application In Synthesis of 1-Iodonaphthalene
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com