Guadalupe, Albarran; Rosalba, Ramos-Morales; Edith, Mendoza published an article in 2021. The article was titled 《Oxidation of halobenzenes by OH radical produced radiolytically in aqueous solution》, and you may find the article in Radiation Physics and Chemistry.Recommanded Product: 626-02-8 The information in the text is summarized as follows:
The radiolytic oxidation of aromatic compounds in dilute aqueous solution is due to the electrophilic strength of the •OH that results from the radiolysis of water. This radical is preferentially added to the electron-rich centers in aromatic rings. Therefore, studies of the charge distribution of the hydroxycyclohexadienyl radicals produced by the addition of the •OH to the aromatics can provide information about their charge distribution. In the present work, the radiolytic oxidation reaction of fluorobenzene, chlorobenzene, bromobenzene, and iodobenzene with the •OH in diluted aqueous solutions was studied. The identification and quantification of the radiolytic products thus formed were carried out utilizing HPLC. The yields found for fluorobenzene, chlorobenzene, bromobenzene, and iodobenzene were 0.609, 0.527, 0.508, and 0.501μmol/J, resp. The electron d. distribution in fluorobenzene, chlorobenzene, and bromobenzene was in the following order: for para > ortho > meta >> ipso; however, in iodobenzene, there is a higher electron d. in the “”ortho”” position than in the “”para”” position. From the total reaction rates for the halobenzenes with the •OH, the partial rate constants were obtained for the reaction of the •OH with each of the positions in the halobenzenes. In the part of experimental materials, we found many familiar compounds, such as 3-Iodophenol(cas: 626-02-8Recommanded Product: 626-02-8)
3-Iodophenol(cas: 626-02-8) belongs to organic iodides. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond.Iodo alkanes participate in a variety of organic synthesis reactions, which include the SimmonsSmith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.Recommanded Product: 626-02-8
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com