In 2018,Angewandte Chemie, International Edition included an article by Cheng, Ying; Mueck-Lichtenfeld, Christian; Studer, Armido. Computed Properties of C10H18INO2. The article was titled 《Metal-Free Radical Borylation of Alkyl and Aryl Iodides》. The information in the text is summarized as follows:
A metal-free radical borylation of alkyl and aryl iodides with bis(catecholato)diboron (B2cat2) as the B source under mild conditions is introduced. The borylation reaction is operationally easy to conduct and shows high functional group tolerance and broad substrate scope. Radical clock experiments and d. functional theory calculations provide insights into the mechanism and rate constants for C-radical borylation with B2cat2 are disclosed. The experimental process involved the reaction of tert-Butyl 4-iodopiperidine-1-carboxylate(cas: 301673-14-3Computed Properties of C10H18INO2)
tert-Butyl 4-iodopiperidine-1-carboxylate(cas: 301673-14-3) is one of organic iodides. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond. Iodo alkanes participate in a variety of organic synthesis reactions, which include the SimmonsSmith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.Computed Properties of C10H18INO2
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com