Appa, Rama Moorthy; Ramesh Naidu, Bandameeda; Venkateswarlu, Derangula; Hanafiah, Marlia M.; Lakkaboyana, Sivarama Krishna; Lakshmidevi, Jangam; Venkateswarlu, Katta published their research in Green Chemistry Letters and Reviews in 2021. The article was titled 《Water extract of pomegranate ash-I2 as sustainable system for external oxidant/metal/catalyst-free oxidative iodination of (hetero)arenes》.HPLC of Formula: 63069-48-7 The article contains the following contents:
An added oxidant/metal/catalyst/additive and problematic solvent-free versatile and straightforward protocol was reported for the synthesis of aryl iodides (AIs) using mol. iodine (I2) in water extract of pomegranate ash (WEPA). These transformations were performed at room temperature (rt) and the reactions took place in 5-20 min to give 83-99% yields of aryl iodides. WEPA was characterized by using XPS, EDX, XRF, XRD and FTIR anal. and a plausible mechanism had been established based on these anal. along with some control experiments Further, the products were purified by recrystallization technique. This work with intrinsic sustainability, high substrate feasibility, utilization of biorenewable catalystytic media, ease of execution and separation of products, and added oxidant/catalyst/metal and additive-free conditions might became one among the forefront sustainable procedures in making aryl iodides. The use of waste-derived WEPA as catalystytic media for this iodination was the novelty of this method and might be used these aryl iodides for further in-process transformations (e.g. cross-couplings, nucleophilic reactions, etc.) to access fine chems. In the experiment, the researchers used many compounds, for example, 4-Chloro-2-iodoaniline(cas: 63069-48-7HPLC of Formula: 63069-48-7)
4-Chloro-2-iodoaniline(cas: 63069-48-7) belongs to anime. Aniline, ethanolamines, and several other amines are major industrial commodities used in making rubber, dyes, pharmaceuticals, and synthetic resins and fibres and for a host of other applications. Most of the numerous methods for the preparation of amines may be broadly divided into two groups: (1) chemical reduction (replacement of oxygen with hydrogen atoms in the molecule) of members of several other classes of organic nitrogen compounds and (2) reactions of ammonia or amines with organic compounds.HPLC of Formula: 63069-48-7
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com