Sun, Zenghui; Xue, Shilin; Zhang, Yining; Xin, Shiyang; Guo, Ran; Shi, Xiaowei; Fu, Yan; Guo, Huicai; Liu, Yi; Wang, Lei published the artcile< λ3-Iodane/Lewis Acid Mediated Intramolecular Cross-Nucleophile Coupling of β-Amino Acrylates: Chemodivergent Syntheses of Indole Alkaloidal Frameworks>, COA of Formula: C9H10FIO, the main research area is indole alkaloidal framework chemodivergent synthesis; amino acrylate intramol cross nucleophile coupling Lewis acid catalyst.
Herein, an unprecedented intramol. cross-nucleophile coupling strategy of indole tethered β-amino acrylates using a catalyst system combining λ3-iodanes and Lewis acids to achieve the chemodivergent synthesis of three unique alkaloid skeletons is reported. It was worth noting that the acquisition of spiroindolenines and azepino[4,5-b]indole derivatives was switchable with choice of the Lewis acids. Moreover, the polycyclic spiroindolines containing a lactone fragment could also be accessed for the first time via cross-nucleophile coupling cascade intramol. condensation sequence.
Organic Letters published new progress about Alkaloids Role: SPN (Synthetic Preparation), PREP (Preparation). 1391728-13-4 belongs to class iodides-buliding-blocks, and the molecular formula is C9H10FIO, COA of Formula: C9H10FIO.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com