《Self-Assembly of a Giant Molecular Solomon Link from 30 Subcomponents》 was published in Angewandte Chemie, International Edition in 2014. These research results belong to Schouwey, Clement; Holstein, Julian J.; Scopelliti, Rosario; Zhurov, Konstantin O.; Nagornov, Konstantin O.; Tsybin, Yury O.; Smart, Oliver S.; Bricogne, Gerard; Severin, Kay. SDS of cas: 1008361-77-0 The article mentions the following:
The synthesis of topol. complex structures, such as links and knots, is one of the current challenges in supramol. chem. The so-called Solomon link consists of two doubly interlocked rings. Despite being a rather simple link from a topol. point of view, only few mol. versions of this link have been described so far. Here, the authors report the quant. synthesis of a giant mol. Solomon link from 30 subcomponents. The highly charged structure is formed by assembly of 12 cis-blocked Pt2+ complexes, six Cu+ ions, and 12 rigid N-donor ligands. Each of the two interlocked rings is composed of six repeating Pt(ligand) units, while the six Cu+ ions connect the two rings. With a mol. weight of nearly 12 kDa and a diameter of 44.2 Å, this complex is the largest non-DNA-based Solomon link described so far. Furthermore, it represents a mol. version of a “”stick link””. The experimental process involved the reaction of 3-Bromo-6-iodo-2-methylpyridine(cas: 1008361-77-0SDS of cas: 1008361-77-0)
3-Bromo-6-iodo-2-methylpyridine(cas: 1008361-77-0) belongs to pyridine. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Additionally, pyridine-based natural products continue to be discovered and studied for their properties and to understand their biosynthesis.SDS of cas: 1008361-77-0
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com