The author of 《Continuous-Flow Electrochemical Generator of Hypervalent Iodine Reagents: Synthetic Applications》 were Elsherbini, Mohamed; Winterson, Bethan; Alharbi, Haifa; Folgueiras-Amador, Ana A.; Genot, Celina; Wirth, Thomas. And the article was published in Angewandte Chemie, International Edition in 2019. Electric Literature of C7H7I The author mentioned the following in the article:
An efficient and reliable electrochem. generator of hypervalent iodine reagents has been developed. In the anodic oxidation of iodoarenes to hypervalent iodine reagents under flow conditions, the use of electricity replaces hazardous and costly chem. oxidants. Unstable hypervalent iodine reagents can be prepared easily and coupled with different substrates to achieve oxidative transformations in high yields. The unstable, electrochem. generated reagents can also easily be transformed into classic bench-stable hypervalent iodine reagents through ligand exchange. The combination of electrochem. and flow-chem. advantages largely improves the ecol. footprint of the overall process compared to conventional approaches. In the experiment, the researchers used many compounds, for example, 1-Iodo-4-methylbenzene(cas: 624-31-7Electric Literature of C7H7I)
1-Iodo-4-methylbenzene(cas: 624-31-7) undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid catalyzed by (Ni,Mg)3Si2O5(OH)4 solid-solution nanotubes loaded with palladium.Electric Literature of C7H7I
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com