D’Auria, Maurizio’s team published research in Synthesis in 1995-03-31 | 88105-22-0

Synthesis published new progress about Chlorination. 88105-22-0 belongs to class iodides-buliding-blocks, and the molecular formula is C6H5IO2S, Name: Methyl 5-iodothiophene-2-carboxylate.

D’Auria, Maurizio; Mauriello, Giacomo published the artcile< Reevaluation of benzyltrimethylammonium dichloroiodide, previously reported to be a selective iodinating agent>, Name: Methyl 5-iodothiophene-2-carboxylate, the main research area is benzyltrimethylammonium dichloroiodate chlorination agent; thiophenecarboxylate chloro.

Benzyltrimethylammonium dichloroiodate [N,N,N-trimethylbenzenemethanaminium dichloroiodate(1-)], previously reported as an iodinating agent of thiophenes, appears to be a selective chlorinating agent of both thienyl and furyl derivatives containing a carbonyl group. Treatment of Me 2-thiophenecarboxylate with benzyltrimethylammonium dichloroiodate/ZnCl2/AcOH gave Me 5-iodo-2-thiophenecarboxylate, Me 4,5-diiodo-2-thiophenecarboxylate, and Me 5-chloro-2-thiophenecarboxylate.

Synthesis published new progress about Chlorination. 88105-22-0 belongs to class iodides-buliding-blocks, and the molecular formula is C6H5IO2S, Name: Methyl 5-iodothiophene-2-carboxylate.

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com